Effects of Irradiation and Thermal Annealing on the Mechanical and Microstructural Properties of Bulk Metallic Glasses

A series of ion irradiation and annealing experiments have been performed on Zr52.5Cu17.9Ni14.6Al10Ti5 “BAM-11” and Cu60Zr20Hf10Ti10 bulk metallic glass (BMG) specimens to evaluate their irradiation- and temperature-induced microstructural and mechanical property evolution. These experiments covered four main themes, namely, ion irradiation, neutron irradiation, thermal annealing, and helium implantation. For the ion irradiations, samples were exposed to 9 MeV Ni and 5.5 MeV C ions at temperatures ranging from room temperature to 360 oC. For the Ni ion irradiations the samples were exposed to midrange (~1.5 m depth) doses of 0.5 and 10 displacements per atom (dpa), while the C ion irradiations samples were irradiated to a midrange dose of 0.5 dpa. For the neutron irradiations, samples were irradiated by neutrons (E \u3e 0.1 MeV) at ~70 oC to fluences of 1.4 × 1020 n/cm2 and 1.4 × 1021 n/cm2 (doses of 0.1 and 1 dpa). Thermal annealing experiments involved heating the samples to various temperatures ranging from 25 - 770 oC. For the helium implantation experiments, amorphous and partially crystallized BMGs were exposed to helium fluences of 2 × 1015 and 5 × 1015 cm-2 . The mechanical property and microstructural characterization included nanoindentation, compression testing, bend testing, Xray diffraction (XRD), neutron diffraction, thermal desorption analysis (TDS), and nuclear reaction analysis. From the experiments, several important conclusions were obtained. The results of the XRD and nanoindentation characterizations of the ion irradiated and thermal annealed specimens indicate good stability during irradiation at 25 to 290 oC up to at least 10 dpa but suggest that the BAM-11 BMG is not suitable for irradiation environments where temperatures exceed 300 oC for prolonged periods of time. As for the neutron irradiation and thermal annealing experiments, significant softening was observed in the sample irradiated by neutrons, while postirradiation annealing led to a marked increase in hardening. Neutron diffraction results indicated vi that primary knock-on events caused rejuvenation (disordering) while annealing resulted in structural relaxation. The results of the TDS experiments found that for the lower He implantation fluence, He desorbed more quickly in the partially crystallized alloy, indicating a structural effect on the mobility of He

Scaling and complexity of stress fluctuations associated with smooth and jerky flow in a FeCoNiTiAl high-entropy alloy

Recent observations of jerky flow in high-entropy alloys (HEA) revealed a high role of self-organization of dislocations in their plasticity. The present work reports first results of investigation of stress fluctuations during plastic deformation of a FeCoNiTiAl alloy, examined in a wide temperature range covering both smooth and jerky flow. These fluctuations, which accompany the overall deformation behavior representing an essentially slower stress evolution controlled by the work hardening, were processed using complementary approaches comprising the Fourier spectral analysis, the refined composite multiscale entropy, and multifractal formalisms. The joint analysis at distinct scales testified that even a macroscopically smooth plastic flow is accompanied with nonrandom fluctuations, disclosing self-organized dynamics of dislocations. Qualitative changes in such a fine-scale "noise" were found with varying temperature. The observed diversity is significant for understanding the relationships between different scales of plasticity of HEAs and crystal materials in general.Comment: 13 pages main body, 6 figures, 2 appendices, 65 citations (22 pages overall

A Review of the Serrated-Flow Phenomenon and Its Role in the Deformation Behavior of High-Entropy Alloys

High-entropy alloys (HEAs) are a novel class of alloys that have many desirable properties. The serrated flow that occurs in high-entropy alloys during mechanical deformation is an important phenomenon since it can lead to significant changes in the microstructure of the alloy. In this article, we review the recent findings on the serration behavior in a variety of high-entropy alloys. Relationships among the serrated flow behavior, composition, microstructure, and testing condition are explored. Importantly, the mechanical-testing type (compression/tension), testing temperature, applied strain rate, and serration type for certain high-entropy alloys are summarized. The literature reveals that the serrated flow can be affected by experimental conditions such as the strain rate and test temperature. Furthermore, this type of phenomenon has been successfully modeled and analyzed, using several different types of analytical methods, including the mean-field theory formalism and the complexity-analysis technique. Importantly, the results of the analyses show that the serrated flow in HEAs consists of complex dynamical behavior. It is anticipated that this review will provide some useful and clarifying information regarding the serrated-flow mechanisms in this material system. Finally, suggestions for future research directions in this field are proposed, such as the effects of irradiation, additives (such as C and Al), the presence of nanoparticles, and twinning on the serrated flow behavior in HEAs

Relation Between the Defect Interactions and the Serration Dynamics in a Zr-Based Bulk Metallic Glass

For this study, the effects of thermal annealing and compressive strain rate on the complexity of the serration behavior in a Zr-based bulk metallic glass (BMG) was investigated. Here, as-cast and thermally-annealed (300 °C, 1 week) Zr52.5Cu17.9Ni14.6Al10Ti5 BMG underwent room-temperature compression tests in the unconstrained condition at strain rates of 2 × 10−5 s−1 and 2 × 10−4 s−1. The complexity of the serrated flow was determined, using the refined composite multiscale entropy technique. Nanoindentation testing and X-ray diffraction characterization were performed to assess the changes in the microstructure and mechanical properties of the BMG that occurred during annealing. The results indicated that the BMG did not crystallize during annealing in the prescribed heating condition. Nanoindentation tests revealed that annealing led to a significant increase in the depth-dependent nanoindentation hardness and Young’s modulus, which were attributed to the structural relaxation in the glass. Furthermore, both annealing and an increased strain rate resulted in a marked enhancement in the complexity of the serrated flow during compression. It was concluded that the increase in the sample entropy with increasing strain rate is related to an increase in the number of defect interactions during the serrated flow